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The possibility of a transient rheological response to ice age loading, first discussed in the literature of the 1980s, has received renewed attention. Transient behaviour across centennial to millennial timescales has been invoked to reconcile apparently contradictory inferences of steady-state (Maxwell) viscosity based on two distinct data sets from Greenland: Holocene sea-level curves and Global Navigation Satellite System (GNSS) derived modern crustal uplift data. To revisit this issue, we first compute depth-dependent Fréchet kernels using 1-D Maxwell viscoelastic Earth models and demonstrate that the mantle resolving power of the two Greenland data sets is highly distinct, reflecting the differing spatial scale of the associated surface loading: the sea-level records are sensitive to viscosity structure across the entire upper mantle while uplift rates associated with post-1000 CE fluctuations of the Greenland Ice Sheet have a dominant sensitivity to shallow asthenosphere viscosity. Guided by these results, we present forward models which demonstrate that a moderate low viscosity zone beneath the lithosphere in Maxwell Earth models provides a simple route to simultaneously reconciling both data sets by significantly increasing predictions of present-day uplift rates in Greenland whilst having negligible impact on predictions of Holocene relative sea-level curves from the region. Our analysis does not rule out the possibility of transient deformation, but it suggests that it is not required to simultaneously explain these two data sets. A definitive demonstration of transient behaviour requires that one account for the resolving power of the data sets in modelling the glacial isostatic adjustment process.

 

Future sea-level rise poses an existential threat for many river deltas, yet quantifying the effect of sea-level changes on these coastal landforms remains a challenge. Sea-level changes have been slow compared to other coastal processes during the instrumental record, such that our knowledge comes primarily from models, experiments, and the geologic record. Here we review the current state of science on river delta response to sea-level change, including models and observations from the Holocene until 2300 CE. We report on improvements in the detection and modeling of past and future regional sea-level change, including a better understanding of the underlying processes and sources of uncertainty. We also see significant improvements in morphodynamic delta models. Still, substantial uncertainties remain, notably on present and future subsidence rates in and near deltas. Observations of delta submergence and land loss due to modern sea-level rise also remain elusive, posing major challenges to model validation. ▪ There are large differences in the initiation time and subsequent delta progradation during the Holocene, likely from different sea-level and sediment supply histories. ▪ Modern deltas are larger and will face faster sea-level rise than during their Holocene growth, making them susceptible to forced transgression. ▪ Regional sea-level projections have been much improved in the past decade and now also isolate dominant sources of uncertainty, such as the Antarctic ice sheet. ▪ Vertical land motion in deltas can be the dominant source of relative sea-level change and the dominant source of uncertainty; limited observations complicate projections. ▪ River deltas globally might lose 5% (∼35,000 km 2 ) of their surface area by 2100 and 50% by 2300 due to relative sea-level rise under a high-emission scenario. Expected final online publication date for the Annual Review of Earth and Planetary Sciences, Volume 51 is May 2023. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates. 

This manuscript describes the synthesis and characterization of guanine and cytosine‐containing supramolecular copolymers, which are inspired from the guanine and cytosine nucleobase pair in deoxyribonucleic acid. Regioselective Michael‐addition allowed the efficient installation of the nucleobases on acrylate‐containing monomers, which enabled the preparation of a series of nucleobase‐functionalized acrylate andn‐butyl acrylate copolymers using conventional free radical copolymerization. Guanine‐containing copolymers exhibited superior thermal properties, thermomechanical performance, and more defined morphological structure than cytosine‐containing copolymer analogs due to the relatively strong guanine self‐association, thus expanding the potential applications for mechanically reinforced polymeric networks. Blending guanine‐ and cytosine‐containing copolymers formed a supramolecular structure through multiple hydrogen bonding between guanine and cytosine units. The supramolecular blend exhibited intermediate thermomechanical and morphological properties, which suggested that guanine and cytosine units were not fully associated in the random copolymer composition. This work provides valuable fundamental understanding of structure–property‐morphology relationships in acrylic copolymers with the presence of guanine‐cytosine self‐ and complementary interactions, suggesting new understanding in supramolecular design for enhanced mechanical and morphological properties.

 

Recent geochemical evidence confirms the oxidized nature of arc magmas, but the underlying processes that regulate the redox state of the subarc mantle remain yet to be determined. We established a link between deep subduction-related fluids derived from dehydration of serpentinite ± altered oceanic crust (AOC) using B isotopes and B/Nb as fluid proxies, and the oxidized nature of arc magmas as indicated by Cu enrichment during magma evolution and V/Yb. Our results suggest that arc magmas derived from source regions influenced by a greater serpentinite (±AOC) fluid component record higher oxygen fugacity. The incorporation of this component into the subarc mantle is controlled by the subduction system’s thermodynamic conditions and geometry. Our results suggest that the redox state of the subarc mantle is not homogeneous globally: Primitive arc magmas associated with flat, warm subduction are less oxidized overall than those generated in steep, cold subduction zones. 

This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit contained cytosine acrylate (CyA) or post-functionalized ureido cytosine acrylate (UCyA) and the B unit consisted of n-butyl acrylate (nBA). Differential scanning calorimetry revealed two glass transition temperatures, suggesting microphase-separation in the A-AB-A triblock copolymers. Thermomechanical and morphological analysis revealed the effects of hydrogen bonding distribution and strength on the self-assembly and microphase-separated morphology. Dynamic mechanical analysis showed multiple tan delta (δ) transitions that correlated to chain relaxation and hydrogen bonding dissociation, further confirming the microphase-separated structure. In addition, UCyA triblock copolymers possessed an extended modulus plateau versus temperature compared to the CyA analogs due to the stronger association of quadruple hydrogen bonding. CyA triblock copolymers exhibited a cylindrical microphase-separated morphology according to small-angle X-ray scattering. In contrast, UCyA triblock copolymers lacked long-range ordering due to hydrogen bonding induced phase mixing. The incorporation of UCyA into the soft central block resulted in improved tensile strength, extensibility, and toughness compared to the AB random copolymer and A-B-A triblock copolymer comparisons. This study provides insight into the structure-property relationships of A-AB-A supramolecular triblock copolymers that result from tunable association strengths.